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About Formic Acid

Formic acid, also known as methanoic acid, is a colorless liquid with a pungent odor and a highly corrosive property. It is naturally occurring in ant venom and is the simplest carboxylic acid. This compound plays a crucial role in various industries, particularly in the production of leather, textiles, and rubber. It acts as a preservative and antibacterial agent in livestock feed, and its acidity makes it a good descaling agent. Industrially, it's used as a solvent and processing agent.
HS Code
29151100
Chemical Formula
HCOOH
Molar Mass
46.03
CAS Code
64-18-6
Synonyms
Methanoic acid, Hydrogen carboxylic acid, Aminic acid, Formylic acid

What is Formic Acid used for?

Formic acid, a simple carboxylic acid with the formula HCOOH, is used across various industries due to its potent properties. Its applications range from agriculture to pharmaceuticals, showcasing its versatility and importance.

Agriculture

In agriculture, formic acid is used as a preservative for silage and as an antibacterial agent. It helps in lowering the pH, which prevents harmful bacteria from spoiling the silage, ensuring a higher nutritional value in animal feed. Additionally, formic acid is utilized in beekeeping to control the troublesome Varroa mites without harming the bees themselves.

Industrial Applications

Formic acid serves a crucial role in leather production, particularly in tanning. It helps in stabilizing the collagen bonds, making leather soft and durable. It is also employed in the textile industry to control the pH of chemicals used in the dyeing process, ensuring that colors are vivid and long-lasting. Moreover, formic acid is used for the natural rubber coagulation, which is key in producing various rubber products.

Chemical Manufacturing

Another significant use of formic acid is in the production of various chemicals, including formates, which are essential salts and esters used in de-icing, as a buffer in laboratory techniques, and more. It’s also a source of a hydrogen molecule in synthetic organic chemistry, facilitating the production of various synthetic products effectively.

Pharmaceuticals and Cosmetics

In the pharmaceutical industry, formic acid is utilized in the manufacture of active ingredients and excipients in medications. It acts as a preservative and pH adjuster in various formulas, ensuring stability and efficacy of the final products. In cosmetics, it's used for similar purposes, particularly in products that require precise pH adjustments to maintain skin compatibility.

Environment and Safety

Formic acid also plays a role in environmental management. It's used as a natural pesticide and herbicide, offering a less harmful alternative to synthetic chemicals. For safety, its use must adhere to strict guidelines as it can be corrosive and dangerous if mishandled, emphasizing the need for proper handling and storage.

How big is the Formic Acid market?

The market for formic acid has demonstrated considerable growth in the past few years. In 2022, the market size was estimated at about USD 1.01 billion and reached roughly 750 thousand tonnes in volume. With a compound annual growth rate (CAGR) projected between 3.5% to 5.1% through 2032, the industry's future looks promising. During this period, formic acid’s market valuation and demand are expected to grow significantly across various global markets.

Yearly Production and Market Drivers

As of the end of 2023, yearly production was estimated to surpass 916.9 Kilo Tons, with an expectancy to reach around 1202.6 Kilo Tons by the year 2032, assuming a growth rate of approximately 2.97% annually. This growth is primarily driven by industrial applications including agriculture, leather tanning, and textiles among others, which continue to expand especially in developing regions.

Major Exporters and Importers

China has established itself as a leading exporter of formic acid, leveraging its expansive manufacturing sector and cost-efficient production methods. Germany also contributes significantly to the global exports. On the import side, countries like the United States and various European nations are the largest importers, which aligns well with their substantial industrial and agricultural consumption needs.

Price Trends and Economic Implications

The average price per metric ton of formic acid has been volatile, though currently trending upwards as supply tightens and demand increases. In 2023, the price was roughly USD 1,000 per metric ton. Given the growing utilization sectors and constrained production capacities, prices are expected to keep rising in the foreseeable future, influencing market dynamics extensively.

Where do companies source Formic Acid?

When looking to source Formic Acid, it is crucial to consider both the major suppliers and their geographic locations. Being aware of where these suppliers are based can greatly influence both logistical strategies and cost-efficiency for procurement.

Top Suppliers and Their Locations

BASF SE, a prominent player in the formic acid market, operates production facilities in Germany, China, and the USA, making them a versatile choice for global supply needs. Other notable manufacturers include Mudanjiang Fengda Chemicals Co., Ltd. in China and Feicheng Acid Chemicals Co. Ltd., also in China. These suppliers highlight the significant role China plays in the formic acid market.

Purchasing Channels

For businesses looking to purchase Formic Acid, options range from bulk chemical traders like Global Chemical Resources to specialized distributors such as GJ Chemical. These companies offer various grades and packaging options, catering to a wide range of industry needs from leather manufacturing to the production of pesticides and resins.

Formic Acid Supplier Lists

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Is Formic Acid regulated?

Formic acid, also known as methanoic acid, is subject to various regulatory considerations, particularly within the European Union (EU). The regulations focus mainly on its production, handling, transportation, and storage, given its classification as a hazardous substance.

EU Regulations

In the EU, formic acid is regulated under REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals), which requires companies to manage the risks from chemicals and to provide safety information on their use. It is also listed in the CLP (Classification, Labelling and Packaging) Regulation, which stipulates hazard labelling standards.

Tariffs and Trade Considerations

When trading formic acid, it's essential to consider import and export tariffs which can vary depending on the country's regulations and trade agreements. In the EU, this information can be found under the TARIC (Tariff Integrated of the European Community) database, which provides detailed tariff information and how it applies to formic acid.

Where to Find Regulatory Information

For current regulatory information, the European Chemicals Agency (ECHA) website is a primary resource. This site offers comprehensive details on all aspects of chemical management in the EU, including legal frameworks, substance registration, and dossier submissions. Additionally, the EUR-Lex website provides access to all EU legislation, which is useful for understanding the legal context in depth.

Is Formic Acid safe?

Formic acid, also known as methanoic acid, is used widely in various industrial applications, but it must be handled with caution due to its highly corrosive nature and potential health hazards. It is essential to understand the proper safety protocols to ensure safe handling and minimize risks.

Safety Precautions

When working with formic acid, always wear appropriate personal protective equipment (PPE). This includes acid-resistant gloves, goggles, and a face shield to protect against splashes. Ensuring that the work area is well-ventilated is crucial to avoid inhalation of vapors, which can be irritating to the respiratory tract.

First Aid Measures

Immediate action is required in case of exposure. If formic acid comes into contact with the skin, rinse the affected area with plenty of water for at least 15 minutes while removing contaminated clothing. For eye exposure, wash the eyes with water for a minimum of 15 minutes and seek medical attention immediately. Inhalation of vapors requires the person to be moved to fresh air and given medical aid if respiration is difficult.

Storage and Disposal

Formic acid should be stored in a cool, well-ventilated area away from incompatible substances like oxidizers and bases. Containers of formic acid must be tightly closed and properly labeled. Disposal of formic acid should comply with local environmental regulations to prevent environmental contamination.

How do you store and package Formic Acid?

Formic Acid, also known as methanoic acid, is commonly used in various industries, including agriculture, leather processing, and textile manufacturing. Proper packaging and storage is crucial to maintain its quality and ensure safety. This guide provides detailed information about best practices for handling Formic Acid.

Packaging of Formic Acid

Formic Acid is usually packaged in materials that can resist its corrosive nature. Common packaging options include high-density polyethylene (HDPE) drums or canisters, and for bulk transport, stainless steel or lined tanks are preferred. It is available in varying concentrations, with most suppliers offering 85%, 90%, and 99% concentrations, each requiring specific packaging solutions. Packages typically range from small bottles for laboratory use to 1000-liter IBC (Intermediate Bulk Container) tanks for large scale industrial applications.

Storage Conditions for Formic Acid

Storage of Formic Acid should be in a cool, well-ventilated area away from direct sunlight and sources of heat. As a highly corrosive substance, it should be stored separately from bases and oxidizing agents to prevent reactive hazards. Storerooms should be equipped with corrosion-resistant flooring and bunding to contain any spills. Regular inspection for container integrity is a must to prevent leakage and exposure. Ensuring that the storage area meets these requirements will maximize the shelf life and effectiveness of Formic Acid.

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