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About Sodium Hydrosulphide

Sodium hydrosulfide (NaHS) is a chemical compound that appears as a white to yellowish flake or a colorless clear liquid with a strong odor of hydrogen sulfide due to hydrolysis by atmospheric moisture. It is primarily used in the paper industry to enhance the whiteness and smoothness of paper. Additionally, NaHS is employed in water treatment facilities to remove heavy metals and for sulfurous tanning of animal hides, contributing to the cleaning agents & detergents industry by providing these essential functions.
HS Code
283010
Chemical Formula
NaHS
Molar Mass
56.06
CAS Code
16721-80-5
Synonyms
Sodium hydrosulfide, Sodium bisulfide, Sodium hydrogen sulfide, Sodium mercaptan, Bisulfure de sodium

What is Sodium Hydrosulphide used for?

Sodium hydrosulfide (NaHS) is a versatile chemical that plays a crucial role in various industrial processes. Its primary applications span across several sectors including mining, pulp and paper manufacturing, water treatment, and chemical synthesis, among others.

Mining Industry Applications

In the mining industry, sodium hydrosulfide is primarily used for the flotation of copper, lead, and zinc ores. It acts as a depressant for sphalerite and pyrite in the flotation process, helping to increase the yield of valuable metals. Moreover, NaHS is involved in the removal of heavy metals from wastewater, ensuring environmental compliance.

Pulp and Paper Industry

In the pulp and paper industry, NaHS is used mainly in the kraft pulping process. It serves as a cooking agent, helping to dissolve lignin and separate fibers effectively. This facilitates the production of high-quality paper while enhancing the overall efficiency of the process. Sodium hydrosulfide also aids in the bleaching process, contributing to the whiteness and brightness of paper products.

Water Treatment

Sodium hydrosulfide finds significant applications in water treatment processes. It is employed in the removal of heavy metals from industrial wastewaters through chemical precipitation. This application is crucial for ensuring that water discharged from industrial plants meets regulatory standards for environmental protection.

Chemical Synthesis

In the realm of chemical synthesis, NaHS is used as a reagent in the synthesis of organic chemicals. This includes the production of synthetic rubbers, pharmaceuticals, and various organic intermediates. Its role as a nucleophile and a base further supports diverse chemical reactions, adding to its utility in complex industrial chemical processes.

How big is the Sodium Hydrosulphide market?

The Sodium Hydrosulphide market has demonstrated robust growth in recent years, with its market size reaching USD 1.2 Billion in 2023, and projected to climb to USD 1.8 Billion by 2031. This represents a compound annual growth rate (CAGR) of approximately 4% from 2024 to 2031. Markets continued to be influenced by varying factors including its key role in diverse industrial processes.

Yearly Production and Major Drivers

Yearly global production of Sodium Hydrosulphide has been increasing steadily. The growth in production is spurred by its extensive application in sectors such as mining, chemical manufacturing, and water treatment. These industries are the primary verticals driving the upward trajectory in demand and production levels.

Leading Exporters and Importers

China is the most prominent exporter of Sodium Hydrosulphide, owing to its large-scale manufacturing capabilities. It is followed by India, which also plays a significant role in the global market dynamics. On the import front, North America and Europe are significant, especially due to high demand in mining and waste water treatment industries within these regions.

Price Trends

As of the most recent evaluations, the average price of Sodium Hydrosulphide per metric ton has been observed to fluctuate depending on the global market dynamics including raw material availability and production levels. Currently, the trend indicates a slight upward movement in prices, reflecting increased demand across various applications.

Where do companies source Sodium Hydrosulphide?

When sourcing Sodium Hydrosulfide (NaHS), it is crucial to consider not only the quality and reliability of the supplier but also their geographical and logistical capabilities. As an intermediate chemical used in various industrial processes, the consistency and purity levels of Sodium Hydrosulfide can significantly affect production outcomes. It is therefore advisable to choose suppliers with robust manufacturing practices and quality control standards.

Major Suppliers of Sodium Hydrosulfide

  • Merichem Co., USA: Holding the largest market share, they are noted for their high-quality standards and substantial production capacity.
  • Laxmi Industries, India: Known for their competitive pricing and strategic market position in Asia.
  • American Elements, USA: Offers a wide range of chemical products, with a strong emphasis on purity and consistency.
  • Akshya Minerals & Chemicals, India: They focus on tailoring products to specific market needs and maintain rigorous quality controls.

Key Considerations for Trade

Trade and logistical considerations are equally important when sourcing NaHS. Suppliers like Vizag Chemicals in India and TDC from America emphasize global distribution capabilities, ensuring timely delivery across major markets. Understanding freight and import conditions in relation to Sodium Hydrosulfide can help in planning for cost-efficient and reliable supply chains.

Sodium Hydrosulphide Supplier Lists

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Is Sodium Hydrosulphide regulated?

Sodium hydrosulfide (NaHS) regulation is primarily governed by chemical control laws in various jurisdictions, with a particular focus on handling, transportation, and safety measures. In the European Union, NaHS falls under Regulation (EC) No 1907/2006, known as REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals), which mandates chemical substances to be safely managed and registered.

REACH Compliance and Authorization

In order to be compliant with REACH, manufacturers and importers of sodium hydrosulfide in the EU must ensure that their substances are properly registered with the European Chemicals Agency (ECHA). This includes providing detailed information on the toxicity, ecological impact, and safe usage recommendations of NaHS.

Import and Export Regulations

For businesses involved in the import or export of sodium hydrosulfide, understanding the tariff codes is essential. In the EU, the TARIC (Integrated Tariff of the European Union) database provides comprehensive details on tariffs and duties applicable when trading chemical substances like NaHS. Tariffs can vary depending on the originating country and are subject to changes based on geopolitical and economic factors.

Resources for Regulatory Information

For the most current and detailed regulatory information regarding sodium hydrosulfide, the European Chemicals Agency's website is an invaluable resource. It provides access to extensive databases like REACH, CLP (Classification, Labelling and Packaging), and the aforementioned TARIC, facilitating compliance and informed decision-making for businesses and regulators alike.

Is Sodium Hydrosulphide safe?

Sodium hydrosulfide (NaHS) is commonly used in various industrial processes, including pulp and paper manufacturing and ore processing. Handling this chemical requires strict observance of safety measures due to its hazardous nature.

Personal Protective Equipment (PPE)

When handling sodium hydrosulfide, it is vital to wear appropriate personal protective equipment. This includes chemical-resistant gloves, goggles, and clothing to prevent skin and eye contact. Full face protection should be used if there is a risk of splashing.

Handling and Storage

Sodium hydrosulfide should be handled in well-ventilated areas to minimize exposure to harmful fumes. It is hygroscopic and must be stored in air-tight containers to avoid absorption of moisture and release of hydrogen sulfide, a toxic gas. Storage areas should be equipped with spill containment to manage accidental releases effectively.

First Aid Measures

In case of skin or eye contact with sodium hydrosulfide, immediately flush the affected area with plenty of water for at least 15 minutes. Remove contaminated clothing. For inhalation, move the individual to fresh air promptly. If ingestion occurs, do not induce vomiting; seek medical attention immediately.

Emergency Procedures

Spill or leak incidents involving sodium hydrosulfide require immediate attention. Evacuate the area, and avoid actions that may spread dust. Use appropriate neutralizing agents to treat spills, and dispose of waste according to local environmental regulations. Always report any significant incidents to the appropriate emergency services and regulatory bodies.

How do you store and package Sodium Hydrosulphide?

Sodium hydrosulfide (NaHS) is a chemical compound used in various industrial processes, such as paper making, textile manufacturing, and in the mining industry as a flotation agent. Proper packaging and storage are essential to ensure its safety and integrity due to its reactive nature, particularly with moisture and air.

Packaging Options for Sodium Hydrosulfide

Sodium hydrosulfide is commonly packaged in tightly sealed containers to prevent exposure to moisture and air, both of which can cause decomposition of the compound. It is available in various forms including flakes, pellets, and aqueous solutions, and is often packed in drums, bags, or tanks depending on the quantity and concentration of the product. Each packaging type is designed to minimize risk during transport and storage. Resealable drums made of materials resistant to chemical corrosion, such as polyethylene, are frequently used for smaller quantities.

Storage Guidelines for Sodium Hydrosulfide

Storing sodium hydrosulfide requires careful attention to environmental conditions. It should be stored in a cool, dry, well-ventilated area away from direct sunlight and incompatible substances such as acids and oxidizing agents, which can trigger hazardous reactions. The storage area should also be equipped with appropriate spill containment measures to manage accidental releases safely. Regular inspection of the storage containers and area is necessary to identify potential risks like container corrosion or product degradation.

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